Accession Number : ADA117680
Title : Anomalous Reorganization Free Energies in Optical Electron Transfer in Solution.
Descriptive Note : Technical rept.,
Corporate Author : NEW YORK UNIV NY DEPT OF CHEMISTRY
Personal Author(s) : Delahay,Paul
PDF Url : ADA117680
Report Date : Jun 1982
Pagination or Media Count : 24
Abstract : Autoionization bands are observed in the photoelectron emission spectroscopy of aqueous solutions of cyanometalate complexes (Mn, Fe, W, Mo), anions (NO(-)3, ClO(-)4) and cations (Ag(+), Tl(+)). Reorganization free energies for autoionization bands are anomalously low in absolute value (by ca. 1 eV) in comparison with direct transitions to the continuum. Interpretation is based on potential energy profiles and model calculations for the reorganization free energy.
Descriptors : *Electron transfer, *Free energy, *Solutions(Mixtures), *Optical properties, Anions, Ionization, Cations, Photoelectron spectra, Emission spectra, Profiles
Subject Categories : Nuclear Physics & Elementary Particle Physics
Distribution Statement : APPROVED FOR PUBLIC RELEASE