Accession Number : ADA118540

Title :   Kinetics of Hydrogen-Oxygen and Hydrocarbon-Oxygen Reactions.

Descriptive Note : Final scientific rept. 1 Apr 77-30 Jun 81,

Corporate Author : HULL UNIV (ENGLAND) DEPT OF CHEMISTRY

Personal Author(s) : Baldwin,Robert R ; Walker,Raymond W

PDF Url : ADA118540

Report Date : Aug 1981

Pagination or Media Count : 69

Abstract : Rate constants of the H2 + 02 reaction at 500 C hae been refined. Rate constants and Arrhenius parameters for reactions of H atoms and OH radicals with C2-C5 alkanes, 2,2,3,3-tetramethylbutane (TMB) and 2,2,3-trimethylbutane (TRIMB) have been obtained. Detailed studies have been made of the products from the oxidation of 1-butane, n-pentane, neopentane, TMB and TRIMB. Rate constants for R + 02 = conjugate alkene, for homolysis of R Radicals, and for the isomerisation of R02 radicals to hydroperoxyalkyl radicals have been tabulated for a range of radicals.

Descriptors :   *Oxygen, *Hydrogen, *Reaction kinetics, *Hydrocarbons, *Oxidation, Rates, Constants, Aldehydes, Alkenes, Alkanes, Butyl radicals, Carbon monoxide

Subject Categories : Organic Chemistry
      Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE