Accession Number : ADA130904
Title : Hydrothermal Stability of Gamma-Aminopropyltriethoxysilane Coupling Agent on Ground Silicon Powder and E-Glass Fibers.
Descriptive Note : Technical rept.,
Corporate Author : CASE WESTERN RESERVE UNIV CLEVELAND OH DEPT OF MACROMOLECULAR SCIENCE
Personal Author(s) : Culler,S R ; Ishida,H ; Koenig,J L
PDF Url : ADA130904
Report Date : 21 Jul 1983
Pagination or Media Count : 27
Abstract : Diffuse reflectance Fourier transform infrared spectroscopy (Drift) was used to study the hydrothermal stability of silane coupling agents on the surface of E-glass fibers and ground silicon powder. The coupling agent studied was gamma-aminopropyltriethoxysilane (gamma-APS). The concepts of chemisorbed and physisorbed silane coupling agent were explored using the Drift infrared technique. The ground silicon powder was used to model the E-glass fiber/coupling agent system. Using the silicon powder, the structure of the siloxane (Si-O-Si) region of the infrared spectrum (1150 to 1000/cm-1) could be investigated. Water was used to remove the physisorbed coupling agent from the substrate. The amount of chemisorbed silane was found to vary slightly as a function of the coupling agent concentration, heat treatment, pH of the coupling agent on the substrate, and the temperature of the water used to remove the physisorbed coupling agent. Spectroscopic evidence was found for chemical bonding of the chemisorbed silane coupling agents to the surface of the substrate used.
Descriptors : *Silanes, *Coupling(Interaction), Exposure(General), Hot water, Thermal stability, Surfaces, Glass, Fibers, Silicon, Powders, Hydrolysis, Adsorption, Chemisorption, Fourier spectroscopy, Infrared spectroscopy, Diffuse reflection, Siloxanes, Substrates, Chemical bonds, Layers, PH factor
Subject Categories : Organic Chemistry
Atomic and Molecular Physics and Spectroscopy
Distribution Statement : APPROVED FOR PUBLIC RELEASE