Accession Number : ADA131014

Title :   4,6-Dinitrobenzofuroxan, an Important Explosive Intermediate.

Descriptive Note : Technical note,


Personal Author(s) : Spear,Robert J ; Norris,William P ; Read,Roger W

PDF Url : ADA131014

Report Date : Feb 1983

Pagination or Media Count : 15

Abstract : The preparation of 4,6-dinitrobenzofuroxan (DNBF) from either benzofuroxan or picryl chloride is described. Batches of up to 20 g have been obtained in suitable crystalline from via recrystallization from a number of solvents. DNBF exhibits impact and electrostatic sensitivity characteristic of a sensitive secondary, such as RDX, and should be handled accordingly. Ignition of small samples ( less than 200 mg) results only in deflagration; detonation can be achieved by the strong shock from detonating lead azide but power output appears to be significantly lower than RDX.

Descriptors :   *Furoxanes, *Nitro radicals, *Benzyl radicals, *Explosives, *Synthesis(Chemistry), Crystallization, Recrystallization, Solvents, Impact, Electrostatics, Sensitivity, Ignition, Deflagration, Detonations, Lead azides, Canada

Subject Categories : Organic Chemistry
      Ammunition and Explosives

Distribution Statement : APPROVED FOR PUBLIC RELEASE