Accession Number : ADA133102

Title :   Rotational Energy Transfer in Highly Vibrationally Excited Hydrogen Fluoride and Deuterium Fluoride.

Descriptive Note : Summary rept. Jun 82-May 83,

Corporate Author : WISCONSIN UNIV-MADISON DEPT OF CHEMISTRY

Personal Author(s) : Crim,F Fleming

PDF Url : ADA133102

Report Date : 16 Mar 1983

Pagination or Media Count : 7

Abstract : Overtone vibration-laser double resonance measurements have provided new data on vibrational and rotational relaxation in HF(v = 2). These experiments determine the magnitudes of the total vibrational relaxation rate constants for HF(v = 1 and 2) as well as their temperature dependences. Rotational relaxation data come from these measurements as well. The temporal evolution of individual rotational states observed in the double resonance studies provides level-to-level energy transfer rate constants when analyzed using an iterative fitting scheme which incorporates scaling relations among the rate constants.

Descriptors :   *Hydrogen fluoride, *Molecular states, *Energy transfer, Deuterium compounds, Excitation, Molecular vibration, Molecular rotation, Relaxation, Energy levels, Lasers

Subject Categories : Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE