Accession Number : ADA133131

Title :   The Reaction of CH3O2 with NO.

Descriptive Note : Final rept. 28 Sep 78-27 Sep 80,

Corporate Author : PENNSYLVANIA STATE UNIV UNIVERSITY PARK IONOSPHERE RESEARCH LAB

Personal Author(s) : Simonaitis,R ; Heicklen,Julian

PDF Url : ADA133131

Report Date : Mar 1981

Pagination or Media Count : 21

Abstract : The kinetics of reaction 1, CH302 + N0 yield CH30 + N02 were studied in the temperature range of 218deg K to 365deg K using the flash photolysis of C12 in the presence of CH4 and 02 as a source of CH302 radicals. These radicals were monitored by ultraviolet absorption. The rate coefficient k sub 1 = (2.1 + or - 1) x 10 to the minus 12th power exp(380 + or - 250/T)cu cm per sec at 200 Torr total pressure. The reaction is independent of pressure (70 - 600 Torr, mostly CH4) at 296deg K.

Descriptors :   *Methyl radicals, *Nitrogen oxides, *Reaction kinetics, Temperature, Chemical reactions, Methane, Oxidation, Photolysis, Pressure, Kinetics, Rates, Synthesis(Chemistry)

Subject Categories : Organic Chemistry
      Thermodynamics

Distribution Statement : APPROVED FOR PUBLIC RELEASE