Accession Number : ADA136269

Title :   Synthesis and Chemistry of Energetic Metallotetraazadienes.

Descriptive Note : Final rept. 1 Dec 82-30 Sep 83,

Corporate Author : NORTHWESTERN UNIV EVANSTON IL DEPT OF CHEMISTRY

Personal Author(s) : Trogler,W C

PDF Url : ADA136269

Report Date : 02 Sep 1983

Pagination or Media Count : 5

Abstract : New approaches to the synthesis of metallotetraazadienes are described. These include reactions between organic azides and transition metal carbonyl complexes, as well as reactions between metal halide complexes and dilithiated tetrazenes. Attempts to prepare disubstituted tetrazenes by the oxidation of unsymmetrical blocked hydrazines is described. The preparation of super reduced metallotetraazadienes has also been achieved. (Author)

Descriptors :   *Synthesis(Chemistry), *Organometallic compounds, Chemical reactions, Azides, Transition metals, Carbonyl compounds, Metal compounds, Halides, Tetrazenes, Oxidation, Hydrazines, Reduction(Chemistry), Reactivities, Energetic properties

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE