Accession Number : ADA137278

Title :   Detailed Kinetic Studies of Excited and/or Transient Species.

Descriptive Note : Final rept. 1 Jun 82-31 May 83,

Corporate Author : UNIVERSITY OF SOUTHERN CALIFORNIA LOS ANGELES

Personal Author(s) : Wittig,C

PDF Url : ADA137278

Report Date : Jan 1984

Pagination or Media Count : 17

Abstract : Subsequent to the pulsed photolytic (193 nm) production of O(3P) in the presence of CF3I, rapid consecutive reactions lead to the production of IF(X1 sigma 3). All of our measurements are consistent with IF being produced via the reactions: O + CF3I yields OI + CF3 yields F2CO + F, and F + CF3I yields IF + CF3. This route can be quite efficient, and we estimate that 10% of the O(3P) atoms can lead to IF molecules under suitable conditions.

Descriptors :   *Iodine compounds, *Laser materials, *Photochemical reactions, *Kinetics, Laser induced fluorescence, Excitation, Fluorides, Pumping, Quantum chemistry, Reaction kinetics

Subject Categories : Radiation and Nuclear Chemistry
      Lasers and Masers

Distribution Statement : APPROVED FOR PUBLIC RELEASE