Accession Number : ADA137321

Title :   Spectroscopic Determination of the AC Voltammetric Response.

Descriptive Note : Technical rept.,

Corporate Author : UTAH UNIV SALT LAKE CITY DEPT OF CHEMISTRY

Personal Author(s) : Hinman,A S ; McAleer,J F ; Pons,S

PDF Url : ADA137321

Report Date : 06 Jan 1984

Pagination or Media Count : 29

Abstract : It is shown that the spectroscopic response of a redoc system to a sinusoidally modulated potential ramp mirrors the AC voltammetric response. This response, however, contains no contribution from the charging current and is specifically sensitive to individual species in the overall redox process. Thus homogeneous and heterogeneous kinetic behavior of the individual species may be studied. Results are presented for the ferro-ferricyanide systems.

Descriptors :   *Oxidation reduction reactions, *Electrochemistry, *Spectroscopy, Mirrors, Kinetics, Modulation, Voltammetry, Reflection

Subject Categories : Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE