Accession Number : ADA140411

Title :   Rates of Intramolecular Conversions over Low Barriers.

Descriptive Note : Final rept. 1 Dec 79-31 Dec 83,

Corporate Author : CORNELL UNIV ITHACA NY DEPT OF CHEMISTRY

Personal Author(s) : Bauer,S H ; Rosenberg,A ; Lazaar,K I

PDF Url : ADA140411

Report Date : 27 Mar 1984

Pagination or Media Count : 13

Abstract : The product developed under this grant is a series of research reports, two of which have been published, one has been accepted for publication, two have been recently submitted for publication, and one has yet to be completed. Their contents is best summarized by quoting the abstracts of these manuscripts. Topics discussed include: Intramolecular Unsymmetrical Oho Bonds. Thermochemistry; Second Order Rate Constants for Intramolecular Conversions: Application to Gas-Phase NMR Relaxation Times; Intramolecular Conversion Rates Over Low Barriers II. The Alkyl Nitrites; Intermolecular Conversion Over a Low Barrier, III. Gas-Phase NMR Studies of an H-Bond Association; Conversions Over Low Barriers IV. Studies of Formic, Acetic and Thioformic Acids; and Conversions Over Low Barriers. V. The Acetyl-Acetones (Gas Phase).

Descriptors :   *Reaction kinetics, *Molecule molecule interactions, Molecular vibration, Relaxation, Vapor phases, Nuclear magnetic resonance, Isomerization, Oxygen, Hydrogen, Chemical bonds, Thermochemistry, Constants, Conversion, Barriers, Alkyl radicals, Nitrides, Molecular association, Formic acid, Acetic acid, Acetones

Subject Categories : Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE