Accession Number : ADA141255

Title :   Gas-Liquid Correlation of Ionization Energies.

Descriptive Note : Technical rept.,

Corporate Author : NEW YORK UNIV NY DEPT OF CHEMISTRY

Personal Author(s) : Delahay,P ; Dziedzic,A

PDF Url : ADA141255

Report Date : Apr 1984

Pagination or Media Count : 20

Abstract : Ionization potentials of ions and molecules are correlated with the threshold energies of their aqueous solutions for photoelectron emission. Inner- and outer-sphere reorganizations are treated, respectively, in terms of a discrete number of dipoles and a continuous medium model. Calculated and experimental threshold energies are compared for halides and hydroxide ions and water. The threshold and reorganization energies of the hydrated electron are calculated from threshold energies of anions and their absorption spectra for charge transfer to the solvent. (Author)

Descriptors :   *Ionization potentials, *Ions, *Molecules, Electrons, Hydration, Threshold effects, Energy, Solutions(Mixtures), Photoelectrons, Electron emission, Free energy, Dipoles, Halides, Hydroxides, Water, Anions, Absorption spectra, Charge transfer, Solvents, Vapor phases, Liquid phases

Subject Categories : Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE