Accession Number : ADA144933

Title :   Preparation and Properties of Single Crystals of Hydrogen Bis(Phthalocyaninato) Neodymium(III).

Descriptive Note : Technical rept.,

Corporate Author : NORTH CAROLINA UNIV AT CHAPEL HILL DEPT OF CHEMISTRY

Personal Author(s) : Sullivan,B W ; Dominey,R N ; Helms,J H ; Schwartz,M ; Haar,L W ter

PDF Url : ADA144933

Report Date : 15 Aug 1984

Pagination or Media Count : 8

Abstract : Partially oxidized metallomacrocycles yield low-dimensional conducting materials. For example, NiPcI (Pc = phthalocyanine) crystallizes with the formation of stacked, planar NiPc units and exhibits metal-like conductivity parallel to the stacking direction. Lanthanide elements form sandwich-type compounds with phthalocyanine. In this paper, we report the electrochemical synthesis, electrical conductivity, and magnetic behavior of single crystals of bis(c)Nd(III).

Descriptors :   *Synthesis(Chemistry), *Single crystals, Neodymium compounds, Electrical conductivity, Rare earth elements, Phthalocyanines, Electrochemistry, Magnetic properties, Sandwich construction, Stacking

Subject Categories : Inorganic Chemistry
      Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE