Accession Number : ADA148803

Title :   Synthesis and Reactivity of (Bis(trimethylsilyl)Methylene)(Mesityl)Phosphine.

Descriptive Note : Techncial rept.,

Corporate Author : TEXAS CHRISTIAN UNIV FORT WORTH DEPT OF CHEMISTRY

Personal Author(s) : Xie,X M ; Wisian-Neilson,P ; Neilson,R H

PDF Url : ADA148803

Report Date : 12 Dec 1984

Pagination or Media Count : 26

Abstract : Two recent papers have described the synthesis and characterization of a series of P-mesityl substituted phosphorus compounds containing Si-N-P and/or Si-C-P linkages. These systems are of interest, in part, as precursors to new types of low-coordinate phosphorus compounds including (methylene) phosphines, RP-CR2 double bond, and imino (methylene) phosphoranes, RP(-NR)-CR2 double bonds. As an extension of these studies, we report here the synthesis and some derivative reactions of bis(Trimethylsilyl)methylene(mesityl)phosphine.

Descriptors :   *Phosphine, *Methylenes, *Methyl radicals, *Silicon, *Synthesis(Chemistry), Dehydrogenation, Halogenation, Chlorine compounds, Phosphine, Addition reactions, Oxidation reduction reactions

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE