
Accession Number : ADA180022
Title : A Unified Model of Vibraluminescence and Thermal Emission.
Descriptive Note : Technical rept. 30 Jun 8530 Jun 86,
Corporate Author : MISSION RESEARCH CORP SANTA BARBARA CA
Personal Author(s) : Archer,Douglas H.
Report Date : 30 JUN 1986
Pagination or Media Count : 127
Abstract : This report develops a model for determining factors, called delta factors which, when multiplied by the Boltzmann populations for vibrational states of selected molecules, gives the actual state populations under conditions, where excitation and deexcitation occur by a combination of VT collisions, VV collisions, and a radiation field. Specifically included is the excitation of states of infrared (IR)active molecules by VV transfer from any excess population of N2(v=1) and/or O2(v=1) molecules with subsequent emission of radiation called vibraluminescence. The radiation rate from a state of an Infraredactive molecule, including thermal emission, vibraluminescence, photon scatter, and effects due to collision limiting, are then obtained by multiplying the thermal equilibrium emission rate from the state by the associated delta factor. With inclusion of vibrational coupling among states N2, O2, H2O, and CO2 (including 3 minor isotopes), analytical expressions are developed to describe the time dependence of the delta factors following an initial enhancement of the N2(v=1) and O2(v=1) populations by an atmospheric disturbance. Vibrational coupling between N2(1), O2(1) and states of CO, NO, and NO(+) is also considered. The model provides delta factors that permit the calculation of the non equilibrium volume emission rate (thermal + vibraluminescence + photon scatter) from 53 bands of the above species spanning the wavelength region from about 1.4 to 15 micrometers.
Descriptors : *RADIATION, *THERMAL RADIATION, ATMOSPHERIC DISTURBANCES, BOLTZMANN EQUATION, COUPLING(INTERACTION), EMISSION, FREQUENCY, ISOTOPES, MATHEMATICAL ANALYSIS, MOLECULES, PHOTONS, POPULATION, RATES, SCATTERING, THERMAL STABILITY, TIME DEPENDENCE, VIBRATION
Subject Categories : Thermodynamics
Distribution Statement : APPROVED FOR PUBLIC RELEASE