Accession Number : ADA180089

Title :   Inorganic Polymers and the Elimination-Condensation Reaction.

Descriptive Note : Final rept. 1 Jul 78-28 Feb 87,

Corporate Author : STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY

Personal Author(s) : Beachley,O T , Jr

PDF Url : ADA180089

Report Date : 29 Apr 1987

Pagination or Media Count : 53

Abstract : During the course of our research a number of new organo-aluminum, - gallium and -indium compounds have been prepared and fully characterized by elemental analyses, cryoscopic molecular weight measurements, physical properties, chemical properties, infrared and NMR spectroscopy as well as X-ray structural studies. In addition, the kinetics and mechanism of the elimination-condensation reaction, a reaction of fundamental significance to the chemistry of group 13-15 compounds, have been eludicated for several pairs of aluminum-nitrogen and -phosphorus compounds semiconductor materials. Our synthetic studies have provided a variety of new types of compounds as well as new compounds of significance to the formation of semiconductor materials by organo molecular crystal vapor disposition and potentially by liquid crystal vaporization.

Descriptors :   *ELIMINATION REACTIONS, *CONDENSATION REACTIONS, *INORGANIC POLYMERS, CHEMICAL PROPERTIES, CRYOGENICS, MEASUREMENT, MOLECULAR WEIGHT, INDIUM COMPOUNDS, LIQUID CRYSTALS, VAPORIZATION, MATERIALS, PHOSPHORUS COMPOUNDS, SEMICONDUCTORS, STRUCTURAL PROPERTIES, X RAYS, CHEMISTRY, GALLIUM, ALUMINUM COMPOUNDS, ORGANOMETALLIC COMPOUNDS, PHYSICAL PROPERTIES, SYNTHESIS(CHEMISTRY)

Subject Categories : Polymer Chemistry
      Inorganic Chemistry
      Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE