Accession Number : ADA180273

Title :   Nitrolysis of the CN Single Bond and Related Chemistry of Nitro and Nitroso Groups.

Descriptive Note : Annual rept. 1 Jan-31 Dec 86,

Corporate Author : NEW ORLEANS UNIV LA

Personal Author(s) : Boyer, Joseph H.

Report Date : MAR 1987

Pagination or Media Count : 61

Abstract : Contents: Nitrosolysis of Tertiary Amines: Piperidines, Piperazines, Bisdimethylaminoalkanes and Functionalized Methyldialkylamines; 1,2-Dinitrocyclohexene: Nitration of 4-Nitro-N,N-dimethylbenzylamine - Formation of 2-Methyl-6-nitroindazole; The Formation and Facile Conversion of Trityl Phenylcyanomethane Nitronate; Alkylation of Nitroacetronitrile; Dibromonitroacetronitrile and Aromatic Compounds: Formal Nitrocyanocarbene Adducts and Brominations from Nitrocyanocarbene; Conversion of alpha-Aminioacides to alpha-Amino Derivatives of Nitros- and Nitramines; Formal Dinitrocarbene and Nitrosyl Bromine Adducts form Dinitrodibromomethane; Ligand Transfer from Iodibenzene Ditrifluoroacetate to an alpha-Iodiketone.

Descriptors :   *NITROSO COMPOUNDS, *CARBENES, *AMINES, *CYANIDES, ALKYLATION, AROMATIC COMPOUNDS, BROMINE, CHEMISTRY, LIGANDS, NITRAMINES, PIPERAZINES, PIPERIDINES, TRANSFER, NITRILES, NITROGEN COMPOUNDS, OXIDATION, SYNTHESIS(CHEMISTRY), ELECTRON TRANSFER.

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE