Accession Number : ADA183590
Title : Conductive Materials Based on Delocalized Carbanions.
Descriptive Note : Technical rept.,
Corporate Author : PENNSYLVANIA STATE UNIV UNIVERSITY PARK DEPT OF MATERIALS SCIENCE AND ENGINEERING
Personal Author(s) : Hancock,Lawrence F ; Gordon,Bernard , III
PDF Url : ADA183590
Report Date : 01 Aug 1987
Pagination or Media Count : 4
Abstract : Studies on the perparation of organic conductors based on delocalized carbanions are presented. The synthesis of sodium and potassium diphenylmethyl anions and potassium alpha, alpha'-diphenylxylenyl dianion. The anions were characterized by gas chromatographic analysis of protonated quench products. Preliminary DC conductivity measurements indicate a conductivity of .5 cm for diphenylmethyl anion. The synthesis of polyethers containing the diphenylmethyl structural unit are described.
Descriptors : *ORGANIC MATERIALS, *CONDUCTIVITY, *MATERIALS, ANIONS, DIRECT CURRENT, MEASUREMENT, STRUCTURAL MEMBERS, SODIUM, GAS ANALYSIS, GAS CHROMATOGRAPHY, POTASSIUM, POLYETHERS, SYNTHESIS(CHEMISTRY)
Subject Categories : Organic Chemistry
Distribution Statement : APPROVED FOR PUBLIC RELEASE