Accession Number : ADA188386
Title : 1,2,3-Triaminoguanidinium Nitrate: An Alternate Explanation of the Nitrate Anion Disorder.
Descriptive Note : Technical rept.,
Corporate Author : ARMY ARMAMENT RESEARCH DEVELOPMENT AND ENGINEERING CENTER DOVER NJ ARMAMENT ENGINEERING DIRECTORATE
Personal Author(s) : Bracuti, A J
PDF Url : ADA188386
Report Date : Dec 1987
Pagination or Media Count : 21
Abstract : The molecular structure of triaminoguanidinium nitrate was redetermined on the basis of a positionally disordered nitrate ion model and compared with results from the model that assumes dynamic rigid-body motion in the nitrate ion. It was concluded that at room temperature the nitrate ion is undergoing rigid-body motion. It was also recommended that a low temperature structure determination be carried out in conjunction with thermal in order to fully characterize nitrate ion motion-disorder. Keywords: Triaminoguanidinium nitrate, Rigid-body motion, Nitrate ion, X ray diffraction.
Descriptors : *ANIONS, *GUANIDINE NITRATES, *MOLECULAR STRUCTURE, *MOLECULAR VIBRATION, *MOLECULAR ROTATION, AMINES, DETERMINATION, DYNAMICS, IONS, LOW TEMPERATURE, MODELS, NITRATES, ROOM TEMPERATURE, X RAY DIFFRACTION, ORIENTATION(DIRECTION), OXYGEN, ATOMS, CRYSTAL STRUCTURE, PROPELLANTS
Subject Categories : Organic Chemistry
Ammunition and Explosives
Atomic and Molecular Physics and Spectroscopy
Distribution Statement : APPROVED FOR PUBLIC RELEASE