Accession Number : ADA189110

Title :   The Synthesis, Characterization and Structural Studies of In(C5H4Me) by X-Ray Diffraction and Electron Diffraction Techniques and a Reinvestigation of the Crystalline State of In(C5H5) by X-Ray Diffraction Studies.

Descriptive Note : Technical rept.,

Corporate Author : STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY

Personal Author(s) : Beachley, O T , Jr ; Pazik, J C ; Glassman, T E ; Churchill, Melvyn R ; Fettinger, James C

PDF Url : ADA189110

Report Date : 17 Dec 1987

Pagination or Media Count : 50

Abstract : The compound In(C5H4Me) has been prepared from InC1 and Li(C5H4Me) in diethyl ether and fully characterized according to its physical and solubility properties, reaction with dilute HC1, a cryoscopic molecular weight study in cyclohexane, infrared and 1H NMR spectroscopic properties, an X ray structural study and a gas-phase electron diffraction study. In addition, a quantitative X ray structural study has been used to reinvestigate the nature of the solid state of In(C5H5). The compound In(C5H4Me) crystallizes in the centrosymmetric space group P21/n (N0. 14var) with a = 6.1636(14), b = 11.5684(17), c = 9.1723(15)A, beta = 103.561(15), V = 635.78(19)A3 and Z = 4. Organoindium chemistry, Indium compounds, Chemistry, X ray structural studies, Electron diffraction studies, Cyclopentadienyl.

Descriptors :   *CYCLOHEXANES, *DIFFRACTION ANALYSIS, *ELECTRON DIFFRACTION, *INDIUM COMPOUNDS, *X RAY DIFFRACTION, *CYCLIC COMPOUNDS, *DIENES, CHEMISTRY, CRYOGENICS, CRYSTALS, ETHERS, ETHYL RADICALS, MOLECULAR WEIGHT, PHYSICAL PROPERTIES, SOLUBILITY, SPECTROSCOPY, STRUCTURAL PROPERTIES, SYNTHESIS(CHEMISTRY)

Subject Categories : Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE