Accession Number : ADA191248

Title :   Enhanced Oxidation and Solvolysis Reactions in Chemically Inert Microheterogeneous Systems.

Descriptive Note : Periodic Rept. no. 2, Sep-Dec 85,

Corporate Author : ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (SWITZERLAND)

Personal Author(s) : Braun, Andre M

PDF Url : ADA191248

Report Date : 15 Jan 1986

Pagination or Media Count : 11

Abstract : The quantitative analysis of hydrogen peroxide dissolved in microemulsions has been worked out for concentrations ranging from 8 to 10 the the-7th M. The stability of the O/W microemulsion containing lauryl acid sodium slat, cyclohexane, n-butanol and water towards hydrogen peroxide has been tested. Kinetic measurements have been made for oxygen evolution as well as the consumption of hydrogen peroxide. Enhanced oxidation of N-methyl-phenothiazine with singlet oxygen has been found in a O/W microemulsion containing sodium lauryl sulfate, cyclohexane, n-butanol and water.

Descriptors :   *CHEMICAL REACTIONS, *HYDROGEN PEROXIDE, *SOLVOLYSIS, CYCLOHEXANES, EVOLUTION(GENERAL), KINETICS, LAURATES, MEASUREMENT, OXIDATION, OXYGEN, QUANTITATIVE ANALYSIS, SODIUM COMPOUNDS, SULFATES, WATER

Subject Categories : Inorganic Chemistry
      Organic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE