Accession Number : ADA195011
Title : Experiments and Modeling of Multi-Component Fuel Behavior in Combustion.
Descriptive Note : Final rept. Sep 84-Nov 87,
Corporate Author : ADVANCED FUEL RESEARCH INC EAST HARTFORD CT
Personal Author(s) : Solomon, Peter R ; Hamblen, David G ; Serio, Michael A ; Tarantul, Kenneth S ; Markam, James R
PDF Url : ADA195011
Report Date : Mar 1988
Pagination or Media Count : 306
Abstract : A computer model was developed to relate pyrolysis and soot formation to fuel properties. A Fourier Transform-Infrared Spectrometer (FT-IR) was used to characterize the effect of temperature, pressure, reaction time, and hydrogen and oxygen concentration of fuels undergoing pyrolysis. The problem of how to identify and measure the hydrogen available for release during pyrolysis was investigated. A detailed data base of a variety of fuels undergoing pyrolysis was developed. The data base conditions included: temperature 800-1500 C; pressure 1-15 atm; and reaction time 100ms-1 sec. Experimental data results show that fuels decompose to form small hydrocarbon species prior to the onset of soot formation. A hydrocarbon model was extended to include Rice-Kossiakoff-Herzfeld mechanism to predict the decomposition of long chain aliphatics to small molecules. A free radical soot model was developed to predict the growth of soot precursors from the small molecules. Keywords: Combustion pyrolysis model; Soot formation; Fourier transform-infrared spectroscopy; Rice-Kossiakoff-Herzfeld mechanism; Free radical.
Descriptors : *COMBUSTION, *COMPUTERIZED SIMULATION, *FUELS, DATA BASES, DECOMPOSITION, EXPERIMENTAL DATA, HYDROCARBONS, HYDROGEN, PYROLYSIS, GAS TURBINES
Subject Categories : Fuels
Combustion and Ignition
Distribution Statement : APPROVED FOR PUBLIC RELEASE