Accession Number : ADA195682

Title :   Intercalation Reactions of Monovalent and Divalent Cations in V6013 Single Crystals.

Descriptive Note : Technical rept. no. 21, 15 Jul 85-30 May 88,

Corporate Author : MINNESOTA UNIV MINNEAPOLIS CORROSION RESEARCH CENTER

Personal Author(s) : Munshi, M Z ; Gilmour, A ; Owens, B B ; Smyrl, W H

PDF Url : ADA195682

Report Date : Jun 1988

Pagination or Media Count : 2

Abstract : Single Crystal V6013 positive material is being evaluated in this laboratory for the intercalation of polyvalent cations such as Li, Na Zn, Cu etc. The study involves 1) growth of V6O13 single crystals, 2) the reversible behavior V6O13 towards polyvalent cations, 3) evaluation of the thermodynamic EMF vs composition curves and 4) XRD and SEM determination in order to evaluate any structural changes occurring in the V6O13 as a result of cation intercalation. Keywords: Single crystals, Vanadium compounds, Polyvalent cations, Intercalation. (MJM)

Descriptors :   *SINGLE CRYSTALS, *VANADIUM COMPOUNDS, CATIONS, STRUCTURAL PROPERTIES, VALENCE, CATIONS, SINGLE CRYSTALS, STRUCTURAL PROPERTIES, VALENCE, VANADIUM COMPOUNDS

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE