Accession Number : ADA198122

Title :   Synthesis and Charge Transport Properties of Polymers Derived from Oxidation of 1-H-1'(6-pyrrol-1-yl)-hexyl-4,4'-bipyridinium Bis-hexafluorophosphate and Demonstration of a pH Sensitive Microelectrochemical Transistor Derived from the Redox Properties of a Conventional Redox Center.

Descriptive Note : Interim technical rept.,

Corporate Author : MASSACHUSETTS INST OF TECH CAMBRIDGE DEPT OF CHEMISTRY

Personal Author(s) : Shu, Ching-Fong ; Wrighton, Mark S

PDF Url : ADA198122

Report Date : 15 Aug 1988

Pagination or Media Count : 56

Abstract : This article describes the synthesis and electrochemical properties of redox polymers, having a poly-pyrrole backbone and viologen subunits, derived from oxidative electropolymerization of 1-methyl-1'-(6-pyrrol-1-yl)-hexyl-4,4'-bipyridinium, (P-V-Me2+), and 1-H1'-(6-pyrrol-1-y1)-hexyl-4,4'-bipyridinium, (P-V-H2+). Keywords: Pyrroles, Pyridinium. (MJM)

Descriptors :   *CHARGE TRANSFER, *POLYMERS, *PYRIDINES, *PYRROLES, ELECTROCHEMISTRY, OXIDATION REDUCTION REACTIONS, SYNTHESIS(CHEMISTRY), TRANSPORT PROPERTIES

Subject Categories : Polymer Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE