Accession Number : ADA214800
Title : Ion-Molecule Reactions Involving Atmospheric Cluster Ions.
Descriptive Note : Final rept.,
Corporate Author : BRANDEIS UNIV WALTHAM MA DEPT OF CHEMISTRY
Personal Author(s) : Henchman, Michael
Report Date : 02 JUL 1981
Pagination or Media Count : 13
Abstract : During the one-year period of this grant work was conducted on five topics; 1) A Unified Treatment of Proton Transfer and Hydrogen Exchange; 2) The synthesis of H3O (-); 3) Deuterium-Labelling Studies of the reactions MH(+) M (M = H2O, NH3 and CH4) in the temperature range 80-500 K; 4) Calculation of reaction ergicities for isotopic exchange reactions from estimated zero-point energies; and 5) The isotope exchange reactions H(+) + D2 = HD + D(+) and D(+) + H2 = HD + H(+) in the temperature range 200-300 K.
Descriptors : *ATMOSPHERIC CHEMISTRY, *CHARGE TRANSFER, *EXCHANGE REACTIONS, CHEMICAL REACTIONS, CLUSTERING, COMPUTATIONS, HYDROGEN, IONS, MOLECULES, PROTONS.
Subject Categories : Physical Chemistry
Distribution Statement : APPROVED FOR PUBLIC RELEASE