Accession Number : ADA279309

Title :   High Temperature Polymer for Second Order Nonlinear Optics for Photonic Materials.

Descriptive Note : End-of-the-year rept.,

Corporate Author : PURDUE UNIV LAFAYETTE IN SCHOOL OF CHEMICAL ENGINEERING

Personal Author(s) : Lackritz, Hilary S.

Report Date : 12 MAY 1994

Pagination or Media Count : 15

Abstract : We are examining a variety of novel high temperature stable polymers as new materials for second order nonlinear optical (NLO) and photorefractive devices. Current polymers have sufficient optical signal generated by available chromophores, but are not practical for device applications because of limitations in the temporal stability of the dopant orientation in the polymer caused by poor thermal stability of the host. This is a novel approach for developing a new class of photonic materials with superior thermal and temporal stability and is the first attempt to design a second order NLO polymer with controllable, tailorable local physical and electrical properties. A second, equally important goal is to understand the basic polymer physics controlling the thermal and temporal stability of the optical chromophore orientation. This will determine not only the overall efficiency of the materials for device applications, but will generate substantial information about mobility in high temperature stable polymer systems.

Descriptors :   *POLYMERS, *POLYIMIDE PLASTICS, *NONLINEAR OPTICS, PHOTONICS, OPTICAL MATERIALS, HIGH TEMPERATURE, COSTS, CHROMOPHORES.

Subject Categories : Plastics
      Optics
      Polymer Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE