Accession Number : ADA291919
Title : Optimal Control of MoIecular Motion.
Descriptive Note : Final technical rept. 1 Nov 91-31 Oct 94,
Corporate Author : PRINCETON UNIV NJ DEPT OF CHEMISTRY
Personal Author(s) : Rabitz, Herschel
PDF Url : ADA291919
Report Date : 13 JAN 1995
Pagination or Media Count : 8
Abstract : The overall objective of this research is to establish the physical principles for achieving control over molecular motion through the introduction of tailor-made optical fields. During the past year, this effort has involved both basic theoretical developments, as well as selected applications. Particular emphasis was given to establishing the robustness of laser field designs to various inevitable uncertainties and errors that may arise. In addition, an entirely new algorithm based on quantum mechanical tracking was introduced as a basis for a comprehensive treatment for both molecular control, as well as the inversion of controlled dynamics, to learn about the underlying Hamiltonians. The application of these various theoretical efforts was made to high quality ro-vibronic population inversion and the selective dissociation of HCN. Finally, a fundamental controllability algorithm was established, with the capability of assessing whether it is feasible to reach acceptable degrees of control in any particular molecule.
Descriptors : *QUANTUM CHEMISTRY, *MOLECULAR VIBRATION, *MOLECULAR ROTATION, ALGORITHMS, LASER PUMPING, OPTICAL PROPERTIES, OPTIMIZATION, CHEMICAL DISSOCIATION, INVERSION.
Subject Categories : Physical Chemistry
Quantum Theory and Relativity
Distribution Statement : APPROVED FOR PUBLIC RELEASE