Accession Number : ADA295665

Title :   Syntheses, Characterization, Crystal and Molecular Structures and Solution Properties of Et2Ga(C5H5) and EtGa(C5H5) 2.

Descriptive Note : Technical rept.,

Corporate Author : STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY

Personal Author(s) : Beachley, O. T., Jr. ; Rosenblum, Daniel B. ; Churchill, Melvyn R. ; Lake, Charles H. ; Krajkowski, Lynn M.

PDF Url : ADA295665

Report Date : 19 JUN 1995

Pagination or Media Count : 38

Abstract : The compounds Et2Ga(C5H5) and EtGa(C5H5)2 have been prepared by ligand redistribution reactions in pentane solution between appropriate quantities of GaEt3 and Ga(C5H5)3. Both compounds have been fully characterized by elemental analyses, X-ray structural studies, cryoscopic molecular weight studies in benzene solution, mass spectroscopic studies, 1H NMR studies of solutions and 1H NMR studies of the melts. Both compounds exist as pure single compounds in the solid state. jg

Descriptors :   *CRYSTAL STRUCTURE, *SOLUTIONS(GENERAL), *GALLIUM, *MOLECULAR STRUCTURE, *ETHYL RADICALS, BENZENE, METHYL RADICALS, SYNTHESIS, STRUCTURAL ANALYSIS, MOLECULAR WEIGHT, MELTS, ORGANOMETALLIC COMPOUNDS, MASS SPECTROSCOPY, X RAYS, PURITY, HYDROCARBONS, LIGANDS, CRYOGENICS, SOLID STATE CHEMISTRY, PENTANES.

Subject Categories : Organic Chemistry
      Inorganic Chemistry
      Physical Chemistry
      Crystallography
      Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE