Accession Number : ADA299130

Title :   Dichloroborane-Dimethyl Sulfide, A Highly Selective Reducing Agent for Reduction of Organyl Azides to Amines.

Descriptive Note : Technical rept.,

Corporate Author : PURDUE UNIV LAFAYETTE IN

Personal Author(s) : Salunkhe, Ashok M. ; Brown, Herbert C.

PDF Url : ADA299130

Report Date : 19 SEP 1995

Pagination or Media Count : 8

Abstract : Dichloroborane-dimethyl sulfide reduces a variety of organyl azides, including primary, secondary, tertiary alkyl, cycloalkyl, aromatic and benzylic, to the corresponding amines in excellent yields. The reagent is highly selective and many functional groups, such as halogen, ester, nitrile, aliphatic and aromatic nitro, survive in this process. jg p.3

Descriptors :   *AMINES, *SULFIDES, *AZIDES, METHYL RADICALS, ALIPHATIC COMPOUNDS, REDUCTION, AROMATIC COMPOUNDS, ESTERS, NITRILES, CHEMICAL COMPOUNDS, CHLORINE, HALOGENS, ALKYL RADICALS, NITRO RADICALS, BORANES.

Subject Categories : Organic Chemistry
      Inorganic Chemistry
      Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE