Accession Number : ADA302851

Title :   Synthesis and Structural Characterization of Alkyl, Gallium-Phosphorus Compounds, X-Ray Crystal Structures of (Me3CCH2)2(Cl)Ga.P(SiMe3)3, R2GaP(SiMe3)2GaR2Cl(R=Me3CCH2 and Me3SiCH2), and ((R)(X)GaP(SiMe3)2)2 (R=Me3CCH2, X=Cl; R=Me3CCH2, X=Me3CCH2; R=Me3SiCH2,X=Br).

Descriptive Note : Technical rept.,

Corporate Author : DUKE UNIV DURHAM NC DEPT OF CHEMISTRY

Personal Author(s) : Wells, Richard L. ; Balwin, Ryan A. ; White, Peter S. ; Pennington, William T. ; Rheingold, Arnold L.

PDF Url : ADA302851

Report Date : 20 DEC 1995

Pagination or Media Count : 35

Abstract : Continued activity in the development of single-source precursors to 13-15 semiconductor materials has motivated our laboratory to investigate the synthesis of novel organogallium phosphorus compounds which might serve as potential precursors to GaP. Recently, our efforts to produce the gallium-phosphorus bond have led to the formation of interesting ring compounds and simple adducts.

Descriptors :   *CRYSTAL STRUCTURE, *X RAYS, *GALLIUM COMPOUNDS, *ALKYL RADICALS, *PHOSPHORUS COMPOUNDS, METHYL RADICALS, SYNTHESIS, SILICON, CHLORIDES, HALIDES, MOLECULAR STRUCTURE, RINGS, BROMIDES, CYCLIC COMPOUNDS.

Subject Categories : Inorganic Chemistry
      Organic Chemistry
      Physical Chemistry
      Crystallography

Distribution Statement : APPROVED FOR PUBLIC RELEASE