Accession Number : ADA308075

Title :   Synthesis Characterization and X-Ray Structural Study of a Dinuclear Organoindium Phosphide Complex with Two Different Phosphide Moieties (Me3CCH2)2InP(t-Bu)2 In(CH2CMe3)2PPh2.

Descriptive Note : Technical rept.,

Corporate Author : STATE UNIV OF NEW YORK AT BUFFALO DEPT OF CHEMISTRY

Personal Author(s) : Beachley, O. T., Jr. ; Chao, Sun-Hua L. ; Churchill, Melvyn R. ; Lake, Charles H.

PDF Url : ADA308075

Report Date : 03 MAY 1996

Pagination or Media Count : 18

Abstract : An organoindium phosphide which incorporates two phosphido moieties in the same molecule (Me3CCH2)2InP(t-Bu)2In(CH2CMe3)2PPh2, 1, has been synthesized in good yield from (Me3CCH2)2InP(t-Bu)22 and (Me3CCH2)2InPPh2 in pentane solution and fully characterized. The compound exists as a single compound in the solid state according to an X-ray structural study but is in equilibrium with the starting compounds in benzene solution according to (1)H and (31)P NMR spectral data. p1

Descriptors :   *STRUCTURAL PROPERTIES, *X RAYS, *ORGANIC COMPOUNDS, *PHOSPHIDES, *INDIUM PHOSPHIDES, *INDIUM, BENZENE, COMPLEX COMPOUNDS, NUCLEAR MAGNETIC RESONANCE, SOLUTIONS(MIXTURES), METHYL RADICALS, SYNTHESIS, HYDROGEN, SPECTRA, BUTYL RADICALS, PHOSPHORUS, PENTANES.

Subject Categories : Organic Chemistry
      Inorganic Chemistry
      Physical Chemistry
      Atomic and Molecular Physics and Spectroscopy

Distribution Statement : APPROVED FOR PUBLIC RELEASE