Accession Number : ADA314809
Title : Self-Assembled Semiconducting Polymer Quantum Boxes.
Descriptive Note : Technical rept.,
Corporate Author : ROCHESTER UNIV NY DEPT OF CHEMICAL ENGINEERING
Personal Author(s) : Jenekhe, Samson A. ; Chen, X. L.
PDF Url : ADA314809
Report Date : 09 SEP 1996
Pagination or Media Count : 22
Abstract : Ultrasmall semiconducting polymer quantum boxes having three-dimensional confinement volumes of 1-2 nm (to the 3d power) are prepared by self-organization of blends of an ABA block conjugated copolymer with its component homopolymer A. Optical experiments evidence quantum confinement effects on excitons in the novel low dimensional semiconductors, including observation of new discrete optical transitions in photoluminescence excitation spectra at room temperature, enhanced luminescence, and exceptional temperature and electric field stability of the quasi zero-dimensional excitons. These results provide the first evidence of quantum confinement effects in semiconducting polymers and a general approach to preparing organic semiconductor quantum boxes which have potential applications in molecular and conventional optoelectronic and photonic devices.
Descriptors : *POLYMERS, *QUANTUM THEORY, *SEMICONDUCTORS, OPTICAL PROPERTIES, STABILITY, EXCITATION, PHOTOLUMINESCENCE, BLOCK COPOLYMERS, ELECTRIC FIELDS, ROOM TEMPERATURE, MIXTURES, THREE DIMENSIONAL, SPECTRA, PHOTONS, CONFINEMENT(GENERAL), LUMINESCENCE, EXCITONS, SELF ORGANIZING SYSTEMS.
Subject Categories : Polymer Chemistry
Atomic and Molecular Physics and Spectroscopy
Quantum Theory and Relativity
Distribution Statement : APPROVED FOR PUBLIC RELEASE