Accession Number : ADA325329

Title :   Formation and Structural Characterization of the Mixed-Metal Pnicogen-Bridged Four-Membered Ring Compounds (Et2O)2LiMU-E(SiMe3)22GaH2, E=P, As.

Descriptive Note : Technical rept.,

Corporate Author : DUKE UNIV DURHAM NC DEPT OF CHEMISTRY

Personal Author(s) : Janik, J. F. ; Wells, R. L. ; Young, V. G., Jr. ; Halfen, Jason A.

PDF Url : ADA325329

Report Date : 15 MAY 1997

Pagination or Media Count : 23

Abstract : Two compounds with novel connectivities, (Et2O)2 LiMU-E(SiMe3)22 GaH2, E = P (1), As (2), formally lithium pnictidogallates, were synthesized in the reactions between LiGaH4 and E(SiMe3)3 in diethyl ether via trimethylsilane elimination.

Descriptors :   *SILICON COMPOUNDS, *GALLIUM COMPOUNDS, *ETHYL RADICALS, *LITHIUM COMPOUNDS, *ARSENIC COMPOUNDS, METALS, CRYSTAL STRUCTURE, METHYL RADICALS, SYNTHESIS(CHEMISTRY), NITROGEN, SILANES, ETHERS, RINGS, SOLID STATE CHEMISTRY, PHOSPHORUS COMPOUNDS, ETHYLENE OXIDE.

Subject Categories : Inorganic Chemistry
      Organic Chemistry
      Physical Chemistry
      Crystallography

Distribution Statement : APPROVED FOR PUBLIC RELEASE