Accession Number : ADD010683

Title :   Phosphorous Containing Polymers as Carriers for Transition Metals.

Descriptive Note : Patent,

Corporate Author : DEPARTMENT OF THE NAVY WASHINGTON DC

Personal Author(s) : Allcock,H R ; Fuller,T J ; Evans,T L

Report Date : 07 Jun 1983

Pagination or Media Count : 7

Abstract : Synthesis of new(lithiophenoxy)phosphazene high polymers is described wherein polymers such as poly(dichlorophosphazene) are used as the starting material to prepare poly(organophosphazenes) by reaction thereof with sodium para-bromophenoxide. Poly(organophophazenes) thus obtained are used in a metal-halogen exchange reaction with n-butyllithium. The lithio derivatives thus obtained are used as reactive intermediates for the synthesis of polymers of formulas (NP(OC6H4X-p)x(OC6H4BR)y)n and (NP(OC6H4Li-p)x(OPh)y)n, where X is PPh2, PPh2, PPh2C4H9+Br-,SnPh3, AuPPh3, or COOH.

Descriptors :   *Patents, *Phosphazene, *Polymers, *Transition metals, Synthesis(Chemistry), Crosslinking(Chemistry), Exchange reactions, Halogens, Organic compounds

Subject Categories : Physical Chemistry
      Metallurgy and Metallography
      Plastics

Distribution Statement : APPROVED FOR PUBLIC RELEASE