Accession Number : ADD011543
Title : Amine Salts as Bonding Agents.
Descriptive Note : Patent,
Corporate Author : DEPARTMENT OF THE ARMY WASHINGTON DC
Personal Author(s) : Ducote,M E ; Allen,H C
Report Date : 15 Jan 1985
Pagination or Media Count : 6
Abstract : The polyamine compound, TEPAN, a partially cyanoethylated tetraethylene pentamine, is reacted with a selected ammonium salt to form an adduct of TEPAN and the selected ammonium salt. The ammonium salt is selected from ammonium perchlorate (AP), ammonium nitrate (AN), ammonium sulfate (AS), and ammonium formate (AF). The process for preparation of the adduct comprises reacting a water solution of the selected ammonium salt with TEPAN while stirring at room temperature. A TEPAN-glycidol derivative product is also reacted with the selected oxidizer salt to form an adduct of the TEPAN-glycidol derivative product. The disclosed adducts improve mechanical properties and processibility; of composite propellant composition containing about 88 weight percent solids (ammonium perchlorate, aluminum, and Fe2O3 catalyst), a binder of hydroxy-terminated polybutadiene and dioctyladipate cured with a mixture of isophorone diisocyanate and a trifunctional isocyanate.
Descriptors : *Patents, *Solid rocket propellant binders, Polybutadiene, Amines, Salts, Polymers, Polymers, Mixing, Room temperature, Glycerolization, Boron oxides, Catalysts, Processing, Composite propellants, Hydroxyl radicals, Reaction kinetics, Mechanical properties
Subject Categories : Solid Rocket Propellants
Distribution Statement : APPROVED FOR PUBLIC RELEASE