Accession Number : ADD095268

Title :   Kinetic Data on Gas Phase Unimolecular Reactions,

Corporate Author : NATIONAL STANDARD REFERENCE DATA SYSTEM

Personal Author(s) : Benson, Sidney W ; O'Neal, H Edward

Report Date : Feb 1970

Pagination or Media Count : 648

Abstract : Available rate data on thermally induced, unimolecular, homogeneous gas phase reactions of molecules and free radicals have been reviewed and critically evaluated. Introductory discussion is given of theory and assumptions used in compiling the selected data. Mechanisms of reaction are discussed. The major portion of the work presents selected data, with references, in the form of data sheets (one to two pages per molecule). Preferred values are indicated and discussed. (Author)

Descriptors :   *REACTION KINETICS, *MOLECULE MOLECULE INTERACTIONS, *VAPOR PHASES, MOLECULES, FREE RADICALS, THERMODYNAMIC PROPERTIES, THERMOCHEMISTRY, MOLECULAR STATES, ELECTRON TRANSITIONS, RATES, CONSTANTS, ACTIVATION ENERGY, HEAT OF ACTIVATION, ENTHALPY, ARRHENIUS EQUATION, FISSION, ELIMINATION REACTIONS, CYCLIC COMPOUNDS, ISOMERIZATION, MOLECULAR ROTATION, EXPERIMENTAL DATA

Subject Categories : Physical Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE