Accession Number : ADD095461

Title :   Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry. Supplement 1. CODATA Task Group on Chemical Kinetics. Revision,

Corporate Author : NATIONAL STANDARD REFERENCE DATA SYSTEM

Personal Author(s) : Baulch, D L ; Cox, R A ; Crutzen, P J ; Hampson, R F , Jr ; Kerr, J A

Report Date : Jan 1982

Pagination or Media Count : 174

Abstract : This paper updates and extends a previous critical evaluation of the kinetics and photochemistry of gas phase chemical reactions of neutral species involved in middle atmosphere chemistry (10-55 km altitude) (J. Phys. Chem. Ref. Data 9,295(1980). The work has been carried out by the authors under the auspices of the CODATA Task Group on Chemical Kinetics. Data sheets have been prepared for 228 thermal and photochemical reactions, containing summaries of the available experimental data with notes giving details of the experimental procedures. For each reaction a preferred value of the rate coefficient at 298 K is given together with a temperature dependence where possible. The selection of the preferred value is discussed, and estimates of the accuracies of the rate coefficients and temperature coefficients have been made for each reaction. The data sheets are intended to provide the basic physical chemical data needed as input for calculations which model atmospheric chemistry. A table summarizing the preferred rate data is provided, together with an appendix listing the available data on enthalpies of formation of the reactant and product species. (Author)

Descriptors :   *ATMOSPHERIC CHEMISTRY, *REACTION KINETICS, *PHOTOCHEMICAL REACTIONS, *THERMOCHEMISTRY, VAPOR PHASES, ABSORPTION CROSS SECTIONS, COEFFICIENTS, RATES, TEMPERATURE, CHEMICAL DISSOCIATION, PHOTOLYSIS, QUANTUM CHEMISTRY, ENTHALPY, HEAT OF FORMATION, REACTANTS(CHEMISTRY), CHEMICAL DERIVATIVES, TROPOSPHERE, STRATOSPHERE, TRACE GASES, AIR POLLUTION, TABLES(DATA)

Subject Categories : Atmospheric Physics

Distribution Statement : APPROVED FOR PUBLIC RELEASE