Accession Number : ADD095476

Title :   Tables of Rate Constants for Gas Phase Chemical Reactions of Sulfur Compounds (1971-1980),

Corporate Author : NATIONAL STANDARD REFERENCE DATA SYSTEM

Personal Author(s) : Westley, F

Report Date : May 1982

Pagination or Media Count : 45

Abstract : A table of rate constants for gas phase chemical reactions of sulfur compounds is presented. Specifically, it gives in tabular form the values of the parameters for the modified Arrhenius equation k = AT superscript B exp(-E/RT). The table covers the reactions of sulfur containing molecules and free radicals, S, S2, SO, SO2, SO3, S2O, SH, H2S, CS, CS2, COS, CH3S, Ch3SH, cy-CH2CH2S, CH3SCH2 and a number of thiols, thioethers, and thioesters, with other compounds. The table includes 19 240 distinct chemical reactions. There are 441 rate constants associated with these reactions, distributed as follows: 30 for first order reactions, 377 for second order reactions, and 34 for third order reactions. The kinetic data were compiled from 145 experimental papers and 8 critical reviews published between 1971 and 1980. (Author)

Descriptors :   *REACTION KINETICS, *SULFUR COMPOUNDS, *VAPOR PHASES, *TABLES(DATA), CHEMICAL REACTIONS, CONSTANTS, ARRHENIUS EQUATION, PARAMETERS, VALUE, COMBUSTION, DECOMPOSITION, FREE RADICALS, HYDROCARBONS, HYDROGEN, NITROGEN, OXYGEN

Subject Categories : Inorganic Chemistry

Distribution Statement : APPROVED FOR PUBLIC RELEASE